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We don't currently support buying Hive accounts with Steem, but you can convert Steem to Hive, then use the Hive to buy an account. There's a fixed fee of 4 Hive for buying an account, so you won't lose any more by the two step process.

You should work on supporting buying Hive accounts with Steem. Just because it's deliciously hilarious. And there are a ton of people migrating that have Steem.

Not a bad idea, maybe we'll add it.